My first thought would be that if they have access to manufacturing new fire arms – which I believe the sole survivor can provide The Beatles 61st Anniversary 1960 2021 Thank You For The Memories Signature Shirt – is that they should begin producing M-14’s and .308 (or 7.62) hollow point rounds. If the ncr can produce service rifles I think this should be possible for the minutemen. Assuming m-14’s exist in this universe if not they could go with the M1 Garand mabye? Putting some soldiers in each squad with these might be a nice counter to power armored troops, if the minutemen can greatly outnumber the brotherhood or enclave which I think they could similiar to the ncr.
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Lastly they should adopt some form of fully automatic weapon for dealing with your typical raider/gunner. For this I was thinking they could perhaps adopt the cheaply made institute The Beatles 61st Anniversary 1960 2021 Thank You For The Memories Signature Shirt rifle/laser pistol and produce them as full auto’s. This way they get all of the advantages of laser and full auto weaponry minus a bit of the punch, and they can still afford it. Besides that I’m not sure what could fill this role besides full auto combat rifles or assault rifles(though I prefer thinking of bostons version as .50 cal machine guns).